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The iron pillar of Delhi is 23 feet 8 inches high (7.2 metres) with 16 inches diameter structure, was constructed by a “King Chandra”, probably Chandragupta II, and is currently standing in the Qutb complex at Mehrauli in Delhi, India. It is famous for the rust-resistant composition of the metals used in its construction….

The iron pillar of Delhi

The pillar has attracted the attention of archaeologists and materials scientists because of its high resistance to corrosion and has been called a “testimony to the high level of skill achieved by the ancient Indian iron smiths in the extraction and processing of iron”.

 The corrosion resistance results from an even layer of crystalline iron(III) hydrogen phosphate hydrate forming on the high-phosphorus-content iron, which serves to protect it from the effects of the Delhi climate.

The pillar weighs over 5,865 kg (13,000 lb) and is thought to have been erected in what is now Udayagiri and reused by one of the Gupta monarchs in approximately 402 CE, though the precise date and location are a matter of dispute.

The height of the pillar, from the top of its capital to the bottom of its base, is 7.21 m (23 ft 8 in), 1.12 m (3 ft 8 in) of which is below ground. Its bell pattern capital is 1.07 m (3 ft 6 in) in height, and its bulb-shaped base is 0.71 m (2 ft 4 in) high.

The base rests on a grid of iron bars soldered with lead into the upper layer of the dressed stone pavement. The pillar’s lower diameter is 420 mm (17 in), and its upper diameter is 306 mm (12 in). It is estimated to weigh more than six tonnes (13,228 lb).

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In 1831, the East India Company officer William Elliott made a facsimile of the inscription. Based on this facsimile, in 1834, James Prinsep published a lithograph in the Journal of the Royal Asiatic Society of Great Britain and Ireland (JASB). However, this lithograph did not represent even a single letter of the inscription correctly. Some years later, British engineer T. S. Burt made an ink impression of the inscription. Based on this, in 1838, Prinsep published an improved lithograph in the same journal, with his reading of the script and translation of the text.

Decades later, Bhagwan Lal Indraji made another copy of the inscription on a cloth. Based on this copy, Bhau Daji Lad published a revised text and translation in 1875, in Journal of the Bombay Branch of the Royal Asiatic Society (JBBRAS). This reading was the first one to correctly mention the king’s name as Chandra. In 1888, John Faithfull Fleet published a critical edition of the text in Corpus Inscriptionum Indicarum.

In 1945, Govardhan Rai Sharma dated the inscription to the first half of the 5th century CE, on paleographic grounds. He observed that its script was similar to the writing on other Gupta-era inscriptions, including the ones discovered at Bilsad (415 CE), Baigram (449 CE), and Kahanum (449 CE). R. Balasubramaniam (2005) noted that the characters of the Delhi inscription closely resembled the dated inscriptions of Chandragupta II, found at Udayagiri in Madhya Pradesh.

While the pillar was certainly used as a trophy in building the Quwwat-ul-Islam mosque and the Qutb complex, its original location, whether on the site itself or from elsewhere, is debated.

The iron pillar of Delhi

According to the inscription of king Chandra, the pillar was erected at Vishnupadagiri (Vishnupada). J. F. Fleet (1898) identified this place with Mathura, because of its proximity to Delhi (the find spot of the inscription) and the city’s reputation as a Vaishnavite pilgrimage centre. However, archaeological evidence indicates that during the Gupta period, Mathura was a major centre of Buddhism, although Vaishnavism may have existed there. Moreover, Mathura lies in plains, and only contains some small hillocks and mounds: there is no true giri (hill) in Mathura.

Based on paleographic similarity to the dated inscriptions from Udayagiri, the Gupta-era iconography, analysis of metallurgy and other evidence, Meera Dass and R. Balasubramaniam (2004) theorized that the iron pillar was originally erected at Udayagiri. According to them, the pillar, with a wheel or discus at the top, was originally located at the Udayagiri Caves.

This conclusion was partly based on the fact that the inscription mentions Vishnupada-giri (IAST: Viṣṇupadagiri, meaning “hill with footprint of Viṣṇu”). This conclusion was endorsed and elaborated by Michael Willis in his Archaeology of Hindu Ritual, published in 2009.The key point in favour of placing the iron pillar at Udayagiri is that this site was closely associated with Chandragupta and the worship of Vishnu in the Gupta period.

In addition, there are well-established traditions of mining and working iron in central India, documented particularly by the iron pillar at Dhar and local place names like Lohapura and Lohangī Pīr (see Vidisha). The king of Delhi, Iltutmish, is known to have attacked and sacked Vidisha in the thirteenth century and this would have given him an opportunity to remove the pillar as a trophy to Delhi, just as the Tughluq rulers brought Asokan pillars to Delhi in the 1300s.

The iron pillar of Delhi

It is not certain when the pillar was moved to Delhi from its original location. Alexander Cunningham attributed the relocation to the Tomara king Anangpal, based on the short pillar inscription ascribed to this king. Pasanaha Chariu, an 1132 CE Jain Apabhramsha text composed by Vibudh Shridhar, states that “the weight of his pillar caused the Lord of the Snakes to tremble”. The identification of this pillar with the iron pillar lends support to the theory that the pillar was already in Delhi during Anangpal’s reign.

Another theory is that the relocation happened during the Muslim rule in Delhi. Some scholars have assumed that it happened around 1200 CE, when Qutb al-Din Aibak commenced the construction of the Qutb complex as a general of Muhammad of Ghor. Finbarr Barry Flood (2009) theorizes that it was Qutb al-Din’s successor Iltutmish (r. 1210–1236 CE), who moved the pillar to Delhi.

The pillar was manufactured by the forge welding of pieces of wrought iron. In a report published in the journal Current Science, R. Balasubramaniam of the IIT Kanpur explains how the pillar’s resistance to corrosion is due to a passive protective film at the iron-rust interface.

The presence of second-phase particles (slag and unreduced iron oxides) in the microstructure of the iron, that of high amounts of phosphorus in the metal, and the alternate wetting and drying existing under atmospheric conditions are the three main factors in the three-stage formation of that protective passive film.

Lepidocrocite and goethite are the first amorphous iron oxyhydroxides that appear upon oxidation of iron. High corrosion rates are initially observed. Then, an essential chemical reaction intervenes: slag and unreduced iron oxides (second phase particles) in the iron microstructure alter the polarisation characteristics and enrich the metal–scale interface with phosphorus, thus indirectly promoting passivation of the iron (cessation of rusting activity). The second-phase particles act as a cathode, and the metal itself serves as anode, for a mini-galvanic corrosion reaction during environment exposure.

Part of the initial iron oxyhydroxides is also transformed into magnetite, which somewhat slows down the process of corrosion. The ongoing reduction of lepidocrocite and the diffusion of oxygen and complementary corrosion through the cracks and pores in the rust still contribute to the corrosion mechanism from atmospheric conditions.

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The iron pillar in Qutb Minar, c. 1905

The next main agent to intervene in protection from oxidation is phosphorus, enhanced at the metal–scale interface by the same chemical interaction previously described between the slags and the metal. The ancient Indian smiths did not add lime to their furnaces.

The use of limestone as in modern blast furnaces yields pig iron that is later converted into steel; in the process, most phosphorus is carried away by the slag.The absence of lime in the slag and the use of specific quantities of wood with high phosphorus content (for example, Cassia auriculata) during the smelting induces a higher phosphorus content (> 0.1%, average 0.25%) than in modern iron produced in blast furnaces (usually less than 0.05%). One analysis gives 0.10% in the slags for 0.18% in the iron itself.

This high phosphorus content and particular repartition are essential catalysts in the formation of a passive protective film of misawite (d-FeOOH), an amorphous iron oxyhydroxide that forms a barrier by adhering next to the interface between metal and rust. Misawite, the initial corrosion-resistance agent, was thus named because of the pioneering studies of Misawa and co-workers on the effects of phosphorus and copper and those of alternating atmospheric conditions in rust formation.

The most critical corrosion-resistance agent is iron hydrogen phosphate hydrate (FePO4-H3PO4-4H2O) under its crystalline form and building up as a thin layer next to the interface between metal and rust. Rust initially contains iron oxide/oxyhydroxides in their amorphous forms. Due to the initial corrosion of metal, there is more phosphorus at the metal–scale interface than in the bulk of the metal.

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Alternate environmental wetting and drying cycles provide the moisture for phosphoric-acid formation. Over time, the amorphous phosphate is precipitated into its crystalline form (the latter being therefore an indicator of old age, as this precipitation is a rather slow happening). The crystalline phosphate eventually forms a continuous layer next to the metal, which results in an excellent corrosion resistance layer. In 1,600 years, the film has grown just one-twentieth of a millimetre thick.

In 1969, in his first book, Chariots of the Gods?Erich von Däniken cited the absence of corrosion on the Delhi pillar and the unknown nature of its creation as evidence of extraterrestrial visitation.When informed by an interviewer, in 1974, that the column was not in fact rust-free, and that its method of construction was well-understood, von Däniken responded that he no longer considered the pillar or its creation to be a mystery.

Balasubramaniam states that the pillar is “a living testimony to the skill of metallurgists of ancient India”. An interview with Balasubramaniam and his work can be seen in the 2005 article by the writer and editor Matthew Veazey. Further research published in 2009 showed that corrosion has developed evenly over the surface of the pillar.

It was claimed in the 1920s that iron manufactured in Mirjati near Jamshedpur is similar to the iron of the Delhi pillar.Further work on Adivasi (tribal) iron by the National Metallurgical Laboratory in the 1960s did not verify this claim.

The iron pillar of Delhi

A significant indentation on the middle section of the pillar, approximately 4 m (13 ft) from the current courtyard ground level, has been shown to be the result of a cannonball fired at close range.The impact caused horizontal fissuring of the column in the area diametrically opposite to the indentation site, but the column itself remained intact.

While no contemporaneous records, inscriptions, or documents describing the event are known to exist, historians generally agree that Nadir Shah is likely to have ordered the pillar’s destruction during his invasion of Delhi in 1739, as he would have considered a Hindu temple monument undesirable within an Islamic mosque complex.Alternatively, he may have sought to dislodge the decorative top portion of the pillar in search of hidden precious stones or other items of value.

No additional damage attributable to cannon fire has been found on the pillar, suggesting that no further shots were taken. Historians have speculated that ricocheting fragments of the cannonball may have damaged the nearby Quwwat-ul-Islam mosque – which is known to have suffered damage to its southwestern portion during the same period – and the assault on the pillar might have been abandoned as a result.

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