A still from Koffee With Karan Season 1. (courtesy: Star World)Koffee With Karan is a pop culture phenomenon thanks to the long list of celebrities who have spoken their heart out on the show. From confessions to catty remarks, filmmaker Karan Johar has managed to get our biggest superstars to let their guard down and speak their minds on the show. Over the years, Karan Johar has managed to get actors – young and old – to have fun and spill some secrets on the famous “Koffee couch”. From best friends to mother-daughter duos, celebrities have landed up in pairs for free-wheeling conversations that have often made headlines.The most endearing of these episodes are the ones featuring real-life couples, who fill the air with love and chemistry.Here’s looking at some of the real-life couples who gave us all some lovely moments on the show:1.Rishi Kapoor and Neetu Kapoor – Season 1, Episode 21The first season of the show saw Rishi Kapoor and Neetu Kapoor open up about the journey first as co-stars, then as partners and finally as husband and wife. Their candid chat with Karan about love and life makes for one fine episode.2.Javed Akhtar and Shabana Azmi – Season 2, Episode 23Veteran Bollywood couple Javed Akhtar and Shabana Azmi won fans over with their chemistry and candour about all things love and life. 3. Shahid Kapoor and Mira Rajput – Season 5, Episode 9Shahid Kapoor and Mira Rajput made their Koffee couch debut as a couple and won a million hearts with their oh-ho-adorable chemistry. From discussing Shahid’s past to recalling their first meeting, the episode was amazing.4. Akshay Kumar and Twinkle Khanna – Season 5, Episode 2This one is our favourite episode. Akshay Kumar and Twinkle Khanna’s offbeat chemistry was a clear winner. Well, we must add that this was the first time when Akshay and Twinkle appeared together on a chat show. 5. Ajay Devgn and Kajol – Season 6, Episode 7Ajay Devgn and Kajol were the funniest on the “Koffee couch”. From how they balance work to giving time to family, the couple, in short, inspired many. Can’t forget the way Ajay and Kajol took a dig at each other. The couple screams goals from miles away.